RELATIONSHIP BETWEEN ANNUAL RUNOFF AND WATERSHED AREA FOR THE EASTERN UNITED STATES1

ABSTRACT: As part of the U.S. Environmental Protection Agency's effort to determine the long-term effects of acidic deposition on surface water chemistry, annual runoff was estimated for about 1000 ungaged sites in the eastern U.S. using runoff contour maps. One concern in using contour maps was that a bias may be introduced in the runoff estimates due to the size of the 1000 ungaged sites relative to the size of the watersheds used in developing the maps. To determine if a bias was present the relationship between the annual runoff (expressed as depth) and the watershed area for the Northeast (NE) and Southern Blue Ridge Province (SBRP) was tested using five regional data bases. One short-term data base (1984 Water Year, n = 531) and two long-term data bases (1940–57, n = 134 and 1951–80, n = 342) were used in the NE. In the SBRP one short-term database (1984 Water Year, n = 531) and one long-term data base (1951–80, n = 60) were used. For the NE and the SBRP, runoff was not directly correlated with watershed area using the five regional databases. Also, runoff normalized by precipitation was not related to watershed area.     

EVAPOTRANSPIRATION DYNAMICS AT AN ECOHYDROLOGICAL RESTORATION SITE: AN ENERGY BALANCE AND REMOTE SENSING APPROACH1

ABSTRACT: Little work is reported where spatial methods are employed to monitor evapotranspiration (ET) changes as a result of vegetation and wetland restoration. A remote sensing approach with the Surface Energy Balance Algorithm for Land (SEBAL) for estimating ET at The Nature Conservancy's Glacial Ridge prairie‐wetland restoration site in northwestern Minnesota is presented. The calibrated 24‐hour ET from SEBAL was estimated with an average error of prediction of ?4.3 percent. Monthly, interseasonal, and seasonal ET for the period of June to September (2000 to 2003) from three adjacent land‐uses: a hydrologic control preserved wetland; a treated or restored site; and a nontreated or impacted wetland, were used in the study. Results from comparing ET behavior to the preserve suggest restoration efforts have affected monthly and seasonal ET within the treated site. Spatial average standard deviations of the seasonal ET within the preserve, treated, and nontreated sites give 47.3, 75.7, and 109.9 mm, respectively, suggesting hydrologic stabilization within the treated site. Monthly and interseasonal comparisons show similar behavior to that of the seasonal data, where monthly correlations suggest increasing agreement within the treated site, approaching those within the preserve.     

Diuron in surface runoff and tile drainage from two grass-seed fields

The typical method of cool-season grass-seed production in Mediterranean climates briefly exposes surface waters to potentially high concentrations of the herbicide diuron [3-(3,4-dichlorophenyl)-1,1-dimethyl urea] during the initial season of growth. To better understand the process, and the degree, of diuron transport from agricultural fields, two grass-seed fields in the Willamette Valley of Oregon were monitored for diuron loss in surface runoff and tile drainage during the first wet season after planting. Initial diuron concentrations in surface runoff were high (>1000 microg L(-1) in one field and >100 microg L(-1) in the other), though they decreased by two orders of magnitude by the end of the season. Concentrations in the tile drains were as much as 1000 times lower than in the surface runoff during the first few weeks of runoff events, and they remained lower than surface water concentrations throughout the season. Total losses in surface runoff were between 1.3 and 3% of the amount applied-much higher than losses via the tile drains. It is also shown by means of a simple first-order decay model that, when little information is available, it may be best to describe diuron depletion in runoff water as a function of cumulative rainfall during the wet season.     

Overexpression of ATP sulfurylase in Indian mustard: effects on tolerance and accumulation of twelve metals

Indian mustard [Brassica juncea (L.) Czern.] transgenics overexpressing ATP sulfurylase (APS plants) were shown previously to have higher levels of total thiols, S, and Se. The present study explores the effect of ATP sulfurylase overexpression on tolerance and accumulation of other metals, both oxyanions and cations, reasoning that some anions may react directly with ATP sulfurylase, while other ions may be bound by its thiol end products. The APS transgenics were compared with wild-type plants with respect to tolerance and accumulation of As, Cd, Cr, Cu, Hg, Mn, Mo, Ni, Pb, V, W, and Zn, supplied individually in agar medium (seedlings) or in hydroponics (mature plants). At the seedling stage, APS transgenics were more tolerant than wild type to As(III), As(V), Cd, Cu, Hg, and Zn, but less tolerant to Mo and V. The APS seedlings had up to 2.5-fold higher shoot concentrations of As(III), As(V), Hg, Mo, Pb, and V, and somewhat lower Cr levels. Mature APS plants contained up to 2.5-fold higher shoot concentrations of Cd, Cr, Cu, Mo, V, and W than wild type. They also contained 1.5- to 2-fold higher levels of the essential elements Fe, Mo, and S in most of the treatments. Mature APS plants showed no differences in metal tolerance compared with the wild type. Overexpression of ATP sulfurylase may be a promising approach to create plants with enhanced phytoextraction capacity for mixtures of metals.     

New Zealand drivers study: developing a methodology for conducting a follow-up study of newly licensed drivers

PROBLEM: In recent years, there has been a significant reduction in traffic crash injury among young people, but they continue to be overrepresented in the traffic crash statistics. To improve this situation, sound scientific evidence is needed to develop effective policies and programs. METHOD: The aim of the proposed study is to provide this evidence by examining early driving and driving-related experiences of newly licensed drivers as they progress through the learner-, restricted-, and full-license stages of the graduated licensing system and to determine the impact of these experiences on subsequent negative traffic-related outcomes (risky driving behavior, injury traffic crashes, noninjury traffic crashes, infringements, convictions). Given the size and complexity of the proposed study, a comprehensive pilot study was undertaken to determine the feasibility of conducting a New Zealand-wide cohort study of newly licensed drivers. RESULTS: This article describes the pilot study process and the methodology that has been developed for the New Zealand-wide study.     

Reduction of arsenic uptake by lettuce with ferrous sulfate applied to contaminated soil

Soil contamination by arsenic (As) presents a hazard in many countries and there is a need for techniques to minimize As uptake by plants. A proposed in situ remediation method was tested by growing lettuce (Lactuca sativa L. cv. Kermit) in a greenhouse pot experiment on soil that contained 577 mg As kg(-1), taken from a former As smelter site. All combinations of iron (Fe) oxides, at concentrations of 0.00, 0.22, 0.54, and 1.09% (w/w), and lime, at concentrations of 0.00, 0.27, 0.68, and 1.36% (w/w), were tested in a factorial design. To create the treatments, field-moist soil, commercial-grade FeSO4, and ground agricultural lime were mixed and stored for one week, allowing Fe oxides to precipitate. Iron oxides gave highly significant (P < 0.001) reductions in lettuce As concentrations, down to 11% of the lettuce As concentration for untreated soil. For the Fe oxides and lime treatment combinations where soil pH was maintained nearly constant, the lettuce As concentration declined in an exponential relationship with increasing FeSO4 application rate and lettuce yield was almost unchanged. Iron oxides applied at a concentration of 1.09% did not give significantly lower lettuce As concentrations than the 0.54% treatment. Simultaneous addition of lime with FeSO4, was essential. Ferrous sulfate with insufficient lime lowered soil pH and caused mobilization of Al, Ba, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Sr, and Zn. At the highest Fe oxide to lime ratios, Mn toxicity caused severe yield loss.     

Tracking chlordane compositional and chiral profiles in soil and vegetation

The cycling of chlordane and other persistent organic pollutants through the environment must be comprehensively elucidated to assess adequately the human health risks posed from such contaminants. In this study the compositional and chiral profiles of weathered chlordane residues in the soil and vegetative compartments were investigated in order to provide details of the fate and transport of this persistent pesticide. Zucchini was planted in a greenhouse in three bays containing chlordane-contaminated soil. At harvest the vegetation and soil were extracted and analyzed for chlordane content using chiral gas chromatography/ion trap mass spectrometry. Both achiral and chiral chlordane components were quantified. The chlordane concentration in the rhizosphere (soil attached to roots) was significantly less than that in the bulk soil. However, the enantiomeric ratio of the chiral components and overall component ratios had changed little in the rhizosphere relative to the bulk soil. Significant levels of chlordane were detected in the vegetation, the amount varying in different plant tissues from a maximum in roots to a minimum in fruit. In addition to the chlordane concentration gradient in plant tissues, significant shifts in compositional profile, as indicated by the component ratios, and in chiral profile, as indicated by the enantiomeric ratio, of the contaminant were observed in the plant tissues. The data indicate that abiotic processes dominate the transport of the chlordane components through the soil to the plant. This is the first report of the effect of rapid biotic processes within the plant compartment on chlordane compositional and chiral profiles.     

Use of Streamflow Data to Estimate Base Flow/Ground‐Water Recharge For Wisconsin1

Abstract: The average annual base flow/recharge was determined for streamflow‐gaging stations throughout Wisconsin by base‐flow separation. A map of the State was prepared that shows the average annual base flow for the period 1970‐99 for watersheds at 118 gaging stations. Trend analysis was performed on 22 of the 118 streamflow‐gaging stations that had long‐term records, unregulated flow, and provided aerial coverage of the State. The analysis found that a statistically significant increasing trend was occurring for watersheds where the primary land use was agriculture. Most gaging stations where the land cover was forest had no significant trend. A method to estimate the average annual base flow at ungaged sites was developed by multiple‐regression analysis using basin characteristics. The equation with the lowest standard error of estimate, 9.5%, has drainage area, soil infiltration and base flow factor as independent variables. To determine the average annual base flow for smaller watersheds, estimates were made at low‐flow partial‐record stations in 3 of the 12 major river basins in Wisconsin. Regression equations were developed for each of the three major river basins using basin characteristics. Drainage area, soil infiltration, basin storage and base‐flow factor were the independent variables in the regression equations with the lowest standard error of estimate. The standard error of estimate ranged from 17% to 52% for the three river basins.